Transportation. But be careful to distinguish "work" from "primary energy". The latter is raw energy content of fuels, maybe 80% of which is wasted when powering (say) a car. Moving to BEVs would reduce total energy use because as much as 5 units of primary energy gets replaced by 1 unit of electrical energy.

A similar effect (if not as dramatic) occurs when replacing a fuel-burning furnace with a heat pump. In the US, 2/3rds of industrial heat demand is below 300 C and could be addressed with industrial heat pumps of various kinds (especially if the process has a waste heat stream to recycle by feeding it into the heat pump.)