There are much easier and cheaper ways of generating megavolts of electricity, I think the biggest barrier would be getting someone who knows enough about this to build it despite their skepticism about the validity of it.
That is what grants are for. And DARPA when something more specific, like this, is to be investigated.
Sure but for creating fairly uniform/gradual fields of static electricity over a large space?
Electrostatic precipitators exist but they aren't large. Everything else I'm aware of that works on larger scales fails to satisfy the uniform/gradual aspect.
I remember hearing about this in the mid 2000s, someone at Brookhaven (US DOE/Army) jumped on filing a patent for it and dubbed it a plasma window.
They found a use for it in particle accelerators to partition off sections that are under vacuum