Free will is about deciding and executing actions contrary to your determined nature:
* Not eating until your body fails.
* Not breathing until automatic breathing kicks in.
And not being able to perform dematerialization doesn't count as non-free will, for example.
Your determined nature is the ability to creat interim goals.
The issue there is that if we are capable of doing something it is hard to say whether or not it is part of our determined nature. For example, maybe we have an evolutionary adaption to famine where elderly people are biologically tweaked to be OK with starving themselves to death. That'd be pretty gruesome and I doubt they'd be excited at the prospect even if a mechanism does exist, but it is the sort of thing that evolution is perfectly capable of encoding into us.
It is less direct to the examples you give; but I'm confident that parents are psychologically designed to sacrifice themselves in the event it helps their children and many men, famously, are built to go to the frontlines and sacrifice themselves for family and community. Hard to make an assessment of whether those sort of choices is free will or determined nature.