You can't prevent spam like that. Rate limiting: based on what key? IP address? Botnets make it irrelevant.
Proof of work? Bots are infinitely patient and scale horizontally, your users do not. Doesn't work.
Micropayments: No such scheme exists.
PoW does seem to work, some Captchas do this already.
Also “identity”, what would that even mean?
PoW does seem to work, some Captchas do this already.