Only finitely many values of BB can be mathematically determined. Once your Turing Machines become expressive enough to encode your (presumably consistent) proof system, they can begin encoding nonsense of the form "I will halt only after I manage to derive a proof that I won't ever halt", which means that their halting status (and the corresponding Busy Beaver value) fundamentally cannot be proven.

> particular values can be calculated

You need proofs of nontermination for machines that don't halt. This isn't possible to bruteforce.