This is completely incorrect. A flat tax has a constant tax rate, which is why it's often referred to as a "proportional tax." Under a true flat tax system, everyone pays the same percentage of their income.
A toll is absolutely regressive because the burden it imposes is constant, irrespective of income; poorer individuals will pay a proportionally higher percentage of their income than wealthier counterparts. As income increases the "effective rate" asymptotically approaches zero, which is regressive by definition.
Good point, I've edited my comment to clarify that it is incorrect