How do you know that those people aren't paying?
OTOH, I don't know how you could effectively enforce that single occupant vehicles are paying.
In Washington state, for one, I know that there used to be a phone number posted periodically for civilian reports of HOV violators. That's gone now with just a warning of the fine amounts.
The FasTrak scanners above the lane flash the occupancy setting (1, 2, or 3+) on the driver's transponder. It's easy to observe cheating single-occupant vehicles because the flashed number is 3 (a toll-free rate).
For automated enforcement, there's prior art in red light camera systems that mail tickets/violations to the registered vehicle owner.