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buildsjetsyesterday at 11:58 PM3 repliesview on HN

Wait up. They propose to convert DDT trapped in the soil to benzene trapped in the soil? Is not benzene also a toxic and persistent soil pollutant (it is) where the typical remediation is to excavate the bad soil and landfill it? (it is)

https://www.waterboards.ca.gov/water_issues/programs/gama/do...

There was an old lady who swallowed a fly, she didn’t know why.


Replies

jjk166today at 12:33 AM

They're not leaving it in the soil. The benzene is extracted as a useful byproduct.

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zdragnartoday at 2:39 AM

The DDT is soluble in DMSO, so it is already possible to separate from soil.

The problem has been that the DDT isn't really useful, so you're still left over with DDT tainted DMSO. Hence, most cleanup efforts focus on sequestration of soil.

The electrolysis step creates benzene and other hydrocarbons, making a useful byproduct. This means there's a better incentive to treat it rather than store it.

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scythetoday at 2:48 AM

Benzene is far more degradable than DDT. In fact the primary reason benzene causes cancer is because the human liver can metabolize it, producing the reactive carcinogen oxepin. It doesn't always degrade fast enough to prevent toxicity to humans or animals, but it doesn't last forever.