Many people are pointing out the toxicity, but the biggest thing that drove me away, especially for specific quantitative questions, was that SO was flat out wrong (and confidently so) on many issues.
It was bad enough that I got back in the habit of buying and building a library of serious reference books because they were the only reliable way to answer detailed technical questions.
If you do not mind my asking, what sorts of questions were you asking that were resulting in wrong answers?