Electric taxiing (on APU) has been in development for over a decade, but it's mostly intended for single aisles (the shorter the flight the more the taxi overhead), and the relatively low fuel prices has led to these projects mostly dying off: L3 shuttered their effort in 2013, Honeywell and Safran's EGTS joint venture was dissolved in 2016, and wheeltug... apparently still lives (with no support from either boeing or airbus), though it was initially supposed to enter service in 2018.
Fuel saving would be only one of the benefits.
Airlines would also significantly reduce engine operating hours, reducing engine wear and thus maintenance costs. I’ve been on flights out of Heathrow that seem to spend almost as much time taxiing as they do in the air (due to weather or ATC delays or whatever), so for short-haul operations this seems really significant.
Local air quality is also a concern for airports: the air in the neighbourhoods around Heathrow often stinks of jet exhaust, sometimes you can smell it from miles away. Presumably, much of those emissions come from taxiing aircraft.