I'm not sure either. It's not an air tight bomb shelter and it's used like an average storeroom, storing stuff like winter jackets, suitcases and paint. I do use small amounts of Calcium Chloride based dessicants to keep the room dry.
Have you checked for Radon?
Water based or solvent based paint?
If it's underground at all, check for radon.
Have you checked for Radon?