> If in a langauge there is one word for 2 different colors, speakers of it are unable to see the difference between the colors.
Perhaps you mean to say that speakers are unable to name the difference between the colours?
I can easily see differences between (for example) different shades of red. But I can't name them other than "shade of red".
I do happen to subscribe to the Sapir-Whorf hypothesis, in the sense that I think the language you think in constrains your thoughts - but I don't think it is strong enough to prevent you from being able to see different colours.
No, if you show them two colors and ask them if they are different, they will tell you no.
EDIT: I have been searching for the source of where I saw this, but can't find it now :(
EDIT2: I found a talk touching in the topic with a study: https://youtu.be/I64RtGofPW8?si=v1FNU06rb5mMYRKj&t=889