The hash technique for uniqueness isn’t supported for indexes because it doesn’t handle hash collisions. The authors proposed solution suffers the same problem- values which do not already exist in the table will sometimes be rejected because they have the same hash as something that was already saved.
This is completely untrue. While the index only stores the hashes, the table itself stores the full value and postgres requires both the hash and the full value to match before rejecting the new row. Ie. Duplicate hashes are fine.