It's a good question, but in a closed system (like you have in space) the heat from the turbine loop has to go somewhere in order to make it useful. Let's say you have a coolant loop for the gpus (maybe glycol). You take the hot glycol, run it through your heat exchanger and heat up your cool, pressurized ammonia. The ammonia gets hot (and now the glycol is cool, send it back). You then take the ammonia and send it through the turbine and it evaporates as it expands and loses pressure to spin the turbine. But now what? You have warm, vaporized, low pressure ammonia, and now you need to cool it down to start over. Once it's cool you can pressurize it again so you can heat it up to use again, but you have to cool it, and that's the crux of the issue.

The problem is essentially that everything you do releases waste heat, so you either reject it, or everything continues to heat up until something breaks. Developing useful work from that heat only helps if it helps reject it, but it's more efficient to reject it immediately.

A better, more direct way to think about this might be to look at the Seebeck effect. If you have a giant radiator, you could put a Peltier module between it and you GPU cooling loop and generate a little electricity, but that would necessarily also create some waste heat, so you're better off cooling the GPU directly.