Your intuition isn’t far off; there is an angle where the weight of green relative to the sum over wavelengths sees a local maximum. But it doesn’t dominate. In that transition zone, there is still an overlapping, transitioning abundance of redder and bluer wavelengths, adding with the green. Consequently, you see red, going into a red+green transition (== oranges, yellows), go into into a green+blue transition (== cyan), which already has few photons relative to the red and yellow zones, so it’s a dark/weak cyan, before it blends into the darker blue of the night sky.