This is most likely because getting a SaaS software to conform to federal regulations and to promise the security needed by the US military is difficult and expensive. FedRAMP is onerous.
And LLM products Are new-ish. It suggests that Anthropic made federal government contracts a priority while OpenAI, Alphabet, AWS didn’t.
They announced it almost a year ago:
https://www.anthropic.com/news/claude-gov-models-for-u-s-nat...
https://support.claude.com/en/articles/13756069-public-secto...