Enhanced mode was already in 3.0 (and I think allowed for flat addressing)
However, Win32s was introduced in 3.11 which a subset of the Windows 32-bit API from NT.
3.11 also introduced 32-bit disk access and 32-bit drivers.
Microsoft did 32-bit in steps -- it was confusing already back then.
> 3.11 also introduced 32-bit disk access and 32-bit drivers.
IIRC a lot of it wasn't turned on by default due to hardware/driver compatability concerns, and there were articles all over the place about how to turn it on for extra performance. Essentially they used optimising tech-heads the world over as a giant beta-test group for parts of Win95's IO subsystem.