That's basically what most software Open Sorce projects state in their licenses as well: Use at your own risk. As someone who publishes design files openly you really don't want to be liable if someone uses the hardware in a wrong way.
That being said, the Libre Solar components are also meant to be used as the basis for customization (hence, called building blocks). Some of the devices are used with minor modifications in certified commercial products.
Apart from boats/caravans, DC systems are used a lot for rural electrification in the global south. This is also where the communication features of Zephyr RTOS are very important.