A bit more reading shows there's a three instruction general case version for 32-bit additions on the 64-bit RISC-V ISA. I'm not familiar with RISC-V assembly and they didn't provide an example, but I _think_ it's as easy as this since 64-bit add wouldn't match the 32-bit overflowed add.

  add t0, t1, t2
  addw t3, t1, t2
  bne t0, t3, overflow