> You still need a dual stack configuration though, there's nothing getting around that when you change the address space

Yes there is, at least outside of the machine. All you need to do is have an internal network (100.64/16, 169.254/16, wherever) local to the machine. If you machine is on say 2001::1, then when an application attempts to listen on an ipv4 address it opens a socket listening on 2001::1 instead, and when an application writes a packet to 1.0.0.1, your OS translates it to ::ffff:100:1. This can be even more hidden than things like internal docker networks.

Your network then has a route to ::ffff:0:0/96 via a gateway (typically just the default router), with a source of 2001::1

When the packet arrives at a router with v6 and v4 on (assume your v4 address is 2.2.2.2), that does a 6:4 translation, just like a router does v4:v4 nat

The packet then runs over the v4 network until it reaches 1.0.0.1 with a source of 2.2.2.2, and a response is sent back to 2.2.2.2 where it is de-natted to a destination of 2001:1 and source of ::ffff:100.1

That way you don't need to change any application unless you want to reach ipv6 only devices, you don't need to run separate ipv4 and ipv6 stacks on your routers, and you can migrate easilly, with no more overhead than a typical 44 nat for rfc1918 devices.

Likewise you can serve on your ipv6 only devices by listening on 2001::1 port 80, and having a nat which port forwards traffic coming to 2.2.2.2:80 to 2001::1 port 80 with a source of ::ffff:(whatever)

(using colons as a deliminator wasn't great either, you end up with http://[2001::1]:80/ which is horrible)