When "the best way to predict the future is to invent it" is combined with crime it seems clear that betting on crime is acting as an accessory. A business facilitating betting on crime is a criminal enterprise, in the sense of RICO.
Polymarket bets on war overshadow a more basic concern:
War prosecuted by a unitary executive without the express consent of the governed is a criminal enterprise.
Trading in such an enterprise is corrupt regardless of its mechanism.
In a global society, the governed are a world-wide body politic, making war fundamentally a racket.