Oh yes, this is what LLMs excel at. Introspecting a database, either the schema or the live data, running a few checks to see whether all the data had the same shape (or how many different shapes it has), writing validations to catch edge cases, they do this extremely quickly and pretty accurately, whereas it would have taken me hours of trawling.
Then I can look at the output and say things like "what if the data is lowercase?" or anything else I suspect they may have missed. A few rounds of these and I have a pretty good feel for the quality of the resulting checks, while taking a few minutes of my attention/tens of minutes of wallclock time to do.
I have a more detailed example here: https://www.stavros.io/posts/how-i-write-software-with-llms/
I'd share all my plans but I once found that the LLM used my actual phone number as test data, so I don't share those any more, just in case.