Regardless of the number of drives available, you gain an advantage when your file system can leverage snapshots to roll backwards or forwards. There are other Linux-native filesystems that can provide this capability too, but many admins prefer ZFS because the full range of capabilities is unparelleled.
Perhaps I'm missing your point, but proxmox+lxc on zfs storage works fine in proxmox? If just looks like any other storage in proxmox and on commandline you've got all the usual zfs tools