I've used OpenSnitch for years, and while LittleSnitch definitely has a better UI for showing which process is making which connections over time, OpenSnitch does a pretty good job here. I get a modal popup when a program that hasn't made a connection tries to make a connection, and I can either allow/deny in one click, or further customize the rule e.g. allowing ntpd to connect, but only to pool.ntp.org on port 123.

Where LittleSnitch is definitely ahead is showing process connections over time after said process has been allowed.