Brazil has had a pretty active program of converting cane sugar to ethanol for a while now.
https://en.wikipedia.org/wiki/Ethanol_fuel_in_Brazil
Sugar cane doesn't require replanting every year either, like corn does.
Plants are actually not a good converter of solar energy to chemical energy though. They capture a few percent of it.
Solar cells are able to capture about 10 times that, a much smaller footprint.
Ethanol is quite a useful thing to have though, as a multi-season stable store of energy. We will need to synthesise it (or other synfuels and feedstocks), to fully transition away from fossil sources, and that 10x efficiency factor will be essential, as synthesis is highly energy-lossy.
What is the conversion efficiency for electricity + C02 + H20 -> ethanol/hydrocarbons?
Because that is the overall path (for long-term storable chemical energy, i.e. usable for transport or seasonal energy storage in countries where solar is highly seasonal).