Maybe you know this, but ElectroBOOM doesn't actually electrocute himself, it's just a running gag.
it's a stupid running gag because some might watch that and think playing with 120V live wire is fine.
It sure seems real to me. although some of those HV circuits like the jacob's ladder seem way too dangerous.
The few I’ve seen were obviously staged but it did appear real in that he was hit with a high voltage. Looking it up suggests that he has been injured a number of times due to miscalculations.