This is how I always imagined FE development would work once ChatGPT 3 came out. Then Cursor appeared and seeing how successful they were with just a chat and a few tool calls, I thought I was over-complicating things.
Anyway, I built a prototype on this idea, but instead of relying only on hover, I press Option to select a node in a custom AST-ish semantic layer I designed around a minimalist UI grammar, and Option + up/down arrows to move to parent/child node. This way, I have have an accurate pointer to the element I want to talk about, plus a minimal context window (parent component, state, a few navigation related queries).
What I learned from using it, though, is that the killer use case isn't necessarily the flashy "talk to this UI element" interaction shown in the Google demos. I do use it that way too; I have `Option + Shift + click` to copy a selector to the clipboard, so I can give an LLM connected to the live medium a precise reference to the element I want to discuss.
But the place where it has been most useful day to day is much simpler: source navigation. Point at the thing in the UI, jump to the code that is responsible for it. The difficult part is jumping to the code you care about (the code for UI or for the semantic element?), but in my system that distinction turned out to be usually obvious, which is what makes the interaction useful.