I think Conway's law is more interesting. It seems natural that networks of human relationships would mirror each other when the same groups of humans translate themselves into a new context.
Whereas the structure of technological products is a "different thing" than the human relationships that created it, it's less obvious that it would translate across that boundary.
> “structure of technological products”
Unless the technology is glued together with ad-hoc systems using email, slack, Dropbox, and the like. At least that’s my experience in small businesses.