I don't know of anyone using sunscreen from the moment they wake up until they go to sleep. Guaranteed that even the best user will still receive a healthy amount of UV even if they refresh every few hours. As far as I'm concerned sunscreen is a 10am-5pm endeavor, not needed before or after
Worth noting here for any readers new to UV guidelines that the above rule isn’t necessarily helpful for you. I’m currently traveling in an area that is 8:30am-4:30pm and live in an area that’s 10-6 pm in the summer and shifts throughout the year.
The actual rule is derived from your location’s safe UV index zones, which is found out by determining what local time the UV Index <= 2. Above 2, wear some amount of protection.