My understanding is that part of the problem with mixing caffine with alcohol is that it can prevent someone from passing out; which is the body's defense mechanism against alcohol poisoning.
From that perspective I think that an argument could be made that restricting caffinated alcohol is regulating substances with known health risks.
Full disclosure: I like vodka Redbulls. So I'm not saying this like I'm someone who is moral panicking.
Four Lokos were indeed banned in Massachusetts.
No, the bodies defense against alcohol is vomiting. "Passing out" increases risk, namely that you vomit while asleep, and then choke on the vomit.