As someone who lives in the Great Lakes region - there are a ton of 100 mile flights that would take 4 hours to drive - often as the first leg in a two-flight trip. Also places like Denver -> Ski resorts (Vail/Aspen/Crested Butte) are 2 - 3hr drives, heavily dependent on road conditions all within the pure-electric range.
>Also places like Denver -> Ski resorts (Vail/Aspen/Crested Butte) are 2 - 3hr drives
See also: Boston and NYC to Cape Cod and the Hamptons.
The electric/green angle helps with these kinds of routes too.
There's regular DEN to COS flights by United, every hour on the hour. Sometimes can be faster than driving, would be a great one to replace. Also ORD to MKE. A lot of small routes that are about 100 miles that are equally inconvenient to drive.