The reals can be ordered, just use x < y. I think you mean that if ZFC is true, we could enumerate unnameable reals (choose one with the axiom of choice, remove it, choose another one, etc.), but you could not enumerate them all. But it is true that you could get a "first" unnameable real.
> The reals can be ordered, just use x < y.
That ordering is not a well-ordering, which is what the GP specified. A well ordering requires that every non-empty subset has a smallest element. That's not true for the reals ordered by x < y: for example, the set of all reals > 0 has no smallest element.
No one has explicitly shown that the reals can be well ordered, but it's a consequence of the axiom of choice that every set can be well-ordered. So in ZFC there must be a well ordering of the reals, even though no one has found one. Issues like this are why not all mathematicians accept the axiom of choice.