I learned to program from block programming, starting out when I was 12. I'm now a full-time developer and funded startup founder. You absolutely can learn complex concepts from simple primitives, and there is a large underground community pushing the limits of languages like Scratch. See for example Linux running on RISC-V running on Scratch:
In my experience, there’s no better way to learn more complex programming techniques or tools than running into a brick wall with the simple tools you’re familiar with, spending a ton of time on an unreasonably irritating solution, only to realize that you’re running into a classic [n] problem and some clever person figured out a simple logical trick to address it. I mean, it can be enraging but that knowledge tends to stick.
Though I doubt that happens much anymore.