> Let's Encrypt is bringing the duration of certs down not up. I believe their goal is 30 minutes validity.
This is mandated by the CA/Browser Forum, which, as the name implies, is related to browsers. It says nothing about e-mail clients. In its Extended Key Usage filed (RFC 5280 § 4.2.1.12) a certificate could not have server or client authentication, but have email protection as an allowed use.
Edit: there is an RFC for "Extensions to Automatic Certificate Management Environment for End-User S/MIME Certificates"