(this is just made up tokenization but it's close enough to the real world)
If the user types <tool_call>, you get < (token id = 32), tool_call (41), > (102). It never decodes to <tool_call>, which is spicy number 12345, for example.
The tool call tokens are _always_ composed of multiple real tokens, so you can never get them from normal text.
Seeing <tool_call> is a bit misleading because that's just a debug rendering if anything. The front-end sees a special number and knows it's a toolcall. The chat template uses that text form because it's easier than writing the spicy numbers there, but it also has a special parsing mode for those.