There's a yttrium-containing variety of LFP that's supposed to work better at lower temperature (down to -45 C). But yttrium itself is quite expensive ($35/kg).

Discharging is not the issue with LiPo4 or other lithium tech. They can work up to negative temperatures without any issue. They can go down to -20°C (-4°F).

The problem is charging the battery at negative, as this damages the internal structure. So you need to heat up the battery (aka, you discharge by warming up heating elements), until you hit the right point. And then you can charge up, what will create heat and thus allow for non-damaging charging.

Some even have a fun trick, where if your going to a EV station with your car (end point route on your build in sat nav). They can start to pre-drain the battery if its really too cold, to warm up the batteries even more. So by the time your at the charger, the batteries are on temperature. I forgot what brand did it that way, seen that feature years ago.

What is different is that Sodium-Ion batteries can charge from negative (i think it was -10°C), as they do not suffer from the same damaging effect.

Lithium can discharge just fine at -25C without heaters.

Charging it at or around 0C will destroy it extremely rapidly due to electroplating of lithium.

lithium batteries can usually discharge below 0C, it's the charging at sub-zero temperatures that kills them.