I don't think off-gassing is a problem, ozone treatment is famously how they get rid of cigarette smell in used cars, furniture and whole apartments.
But I would worry about the effect on e.g. plastic seals. There are a lot of plastics that become brittle with ozone exposure, let alone UV exposure.
I imagine the UV energy itself weathers surfaces like the sun does, but at different scales. It's probably not enough to matter from the lamps.
"Hot car smell" is plastics in the car releasing volatile gas from the heat and sunlight, and surfaces in general fade, peel and crack from sun exposure over time. Thought maybe something like that would happen with different exposed materials to the lamps.